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qid 4607 · chemistry
Question: The equilibrium populations of the 1H energy levels of a molecule are nα = nαeq and nβ = nβeq. What are the populations after a 5.0 μs pulse when B1 = 4.697 mT?
- nα = nβeq/2 and nβ = 2nαeq
- nα = nαeq + 2nβeq and nβ = nβeq + 2nαeq
- nα = 3nαeq and nβ = nβeq/2
- nα = nαeq/3 and nβ = 3nβeq
- nα = nαeq + nβeq and nβ = nαeq + nβeq
- nα = nαeq and nβ = nβeq
- nα = nβeq and nβ = nαeq
- nα = 2nαeq and nβ = 2nβeq
- nα = ½(nαeq + nβeq) and nβ = ½(nαeq + nβeq)
- nα = nαeq - nβeq and nβ = nβeq - nαeq
Our answer: G. nα = nβeq and nβ = nαeq Source quote machine-checked (exact quote)
How it was answered
Multi-step solver (maze), replayed by code
Current source
University of Oxford Department of Chemistry NMR, "Measuring relaxation times: Inversion recovery for T1" (Amin & Claridge, 2019)
https://nmr.chem.ox.ac.uk/files/measuringrelaxationtimespdf
“In the inversion recovery experiment, the nuclei are first allowed to relax fully to their equilibrium states along the z-axis. A 180-degree pulse is then applied, which inverts the signals.”
Source quote machine-checked (exact quote)
Earlier version (superseded)
No public source has been found for this card yet (3 places checked internally).
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